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Npm WARN checkPermissions Missing write access to /usr/lib In situ ATR-FTIR observation and DFT calculations suggest that water molecules' existence significantly lowers the proton/electron transfer energy barrier, which coincides with our experimental observations.Code: Select all $ npm install -g electron At low water content (2 wt%), the PCET reaction follows a concerted pathway with a lower energy barrier, leading to normal KSIEs (H/D) ≥ 2 with both reagents. In this work, we reveal that the amount of adsorbed water molecules determines the photo-induced PCET pathway on the TiO 2 surface through systematic kinetic solvent isotope effect (KSIE) experiments.

Figuring out the specific pathway of semiconductor-mediated proton-coupled electron transfer (PCET) driven by light is essential to solar energy conversion systems.
